Tetrakis(acetonitrile)copper(I) tetrafluoroborate is a complex compound of copper with acetonitrile as the ligand and tetrafluoroborate as the counterion.
Structure Tetrakis(acetonitrile)copper(I) tetrafluoroborate forms colorless crystals in the orthorhombic crystal system in the space group Pna21 with the lattice parameters a = 23.882 Å; b = 8.3285 Å; c = 20.338 Å, and twelve unit cells. The compound is isomorphous with tetrakis(acetonitrile)copper(I) perchlorate and tetrakis(acetonitrile)silver(I) perchlorate.
Preparation Tetrakis(acetonitrile)copper(I) tetrafluoroborate can be prepared starting from nitrosyl tetrafluoroborate according to the following equation:
Cu + NOBF4 + 4 CH3CN → [Cu(CH3CN)4]BF4 + NO The conversion appears to occur in two stages, initially producing a green-blue copper(II) complex. This complex is reduced to the colorless copper(I) complex by further treatment with metallic copper.
Reactions Tetrakis(acetonitrile)copper(I) tetrafluoroborate reacts with methoxyisobutyl isonitrile to produce tetrakis(methoxyisobutylisonitrile)copper(I) tetrafluoroborate:
[Cu(CH3CN)4]BF4 + 4 CH3O(CH3)2CCH2NC → [Cu(CH3O(CH3)2CCH2NC)4]BF4 + 4 CH3CN [Cu(CH3O(CH3)2CCH2NC)4]BF4 is used to produce technetium(99mTc)-sestamibi, which is of commercial value.
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