Tetrakis(cyclopentadienyl)uranium(IV), U(C5H5)4, abbreviated U(Cp)4, is an organouranium compound composed of a uranium atom sandwiched between four cyclopentadienide rings.
Synthesis and properties Tetrakis(cyclopentadienyl)uranium(IV) was first prepared in 1962 by Ernst Otto Fischer, who reacted uranium tetrachloride with excess potassium cyclopentadienide in benzene and obtained the complex as red crystals at 6% yield:
UCl4 + 4 KCp → U(Cp)4 + 4 KCl Solid crystals of U(Cp)4 are air-stable, but the benzene solution is extremely air-sensitive. Reduction of U(Cp)4 with uranium metal yields tris(cyclopentadienyl)uranium(III), U(Cp)3.
References
External links Media related to Tetrakis(cyclopentadienyl)uranium(IV) at Wikimedia Commons


