Tetramethylammonium perchlorate is a perchlorate salt with a chemical formula [(CH3)4N]ClO4. It is a white crystalline powder. It is a quaternary ammonium salt. It consists of tetramethylammonium cations [(CH3)4N]+ and perchlorate anions ClO−4.
Preparation Tetramethylammonium perchlorate can be produced by mixing cold tetramethylammonium hydroxide with cold, dilute perchloric acid, the reaction leads to a white precipitation.
[(CH3)4N]OH + HClO4 → [(CH3)4N]ClO4 + H2O
Uses The perchlorate is used as an intermediate in organic synthesis, in chromatography and as a supporting electrolyte in electrochemistry. Along with trimethylammonium perchlorate, it was investigated as a component in composite propellants during the Cold War, but without much success.
References
Further reading Hofmann, K. A.; Roth, R.; Hobold, K.; Metzler, A. Relationship between the Constitution and Behavior towards Water of Ammonium Oxonium Perchlorates. Berichte der Deutschen Chemischen Gesellschaft, 1911. 43: 2624-2630. ISSN 0365-9496






