Tetramethylammonium sulfate is a chemical compound with the chemical formula [N(CH3)4]2SO4. It is a white hygroscopic crystalline powder. It is a quaternary ammonium salt. It consists of tetramethylammonium cations [N(CH3)4]+ and sulfate anions SO2−4. It forms the tetrahydrate [N(CH3)4]2SO4·4H2O.
Structure Tetramethylammonium sulfate tetrahydrate is orthorhombic, with a space group of Pnam, with the lattice constants a = 15.438 Å, b = 13.832 Å, c = 7.923 Å at −26 °C (−15 °F). The crystal structure contains ordered tetramethylammonium cations in channels formed by hydrogen‐bonded chains of water molecules cross linked by interaction with the sulfate anions which are disordered.
Synthesis Tetramethylammonium sulfate can be synthesized by the reaction between tetramethylammonium hydroxide and sulfuric acid, followed by careful evaporation and crystallization.
2 [N(CH3)4]OH + H2SO4 → [N(CH3)4]2SO4 + 2 H2O
Uses Tetramethylammonium sulfate is used as a phase transfer catalyst and in organic synthesis. It exhibits properties typical of quaternary ammonium compounds, such as being a surfactant and having antimicrobial activity. Zinc metal is considered as a promising metal anode for aqueous rechargeable metal ion batteries due to its low electrochemical potential and high theoretical capacity. However, zinc metal suffers from hydrogen evolution reaction and dendrite growth during plating and stripping. A low-cost, effective and non-toxic electrolyte additive, tetramethylammonium sulfate, as a simple cationic surfactant additive for zinc-ion batteries is proposed, to trigger the smooth zinc deposition during battery charging and discharging. It is found that tetramethylammonium sulfate enables the deposition of zinc cations (Zn2+) along the surface of zinc foil laterally without stacking and thus dendrite growth and side reactions are greatly avoided by the electrolyte additive of tetramethylammonium sulfate.
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