Tetraphenyllead is an organolead compound with the chemical formula Pb(C6H5)4 or PbPh4. It is a white solid.
Preparation Tetraphenyllead can be produced by the reaction of phenylmagnesium bromide and lead(II) chloride in diethyl ether. This was the method first used by P. Pfeiffer and P. Truskier to produce tetraphenyllead in 1904.
(C6H5)MgBr + 2 PbCl2 → Pb(C6H5)4 + Pb + 4 MgBrCl
Reactions A solution of hydrogen chloride in ethanol can react with tetraphenyllead and substitute some of the phenyl groups to chlorine atoms:
Pb(C6H5)4 + HCl → Pb(C6H5)3Cl + C6H6 Pb(C6H5)3Cl + HCl → Pb(C6H5)2Cl2 + C6H6 Just like tetrabutyllead, tetraphenyllead and sulfur react explosively at 150 °C and produce diphenyl sulfide and lead(II) sulfide:
Pb(C6H5)4 + 3 S → PbS + 2 S(C6H5)2 Tetraphenyllead reacts with iodine in chloroform to produce triphenyllead iodide.
Safety Tetraphenyllead may damage fertility or the unborn child, to organs through prolonged or repeated exposure (kidneys, male gonads, liver, central nervous system). Possible carcinogen.
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