Thermal velocity or thermal speed is a typical velocity of the thermal motion of particles that make up a gas, liquid, etc. Thus, indirectly, thermal velocity is a measure of temperature. Technically speaking, it is a measure of the width of the peak in the Maxwell–Boltzmann particle velocity distribution. Note that in the strictest sense thermal velocity is not a velocity, since velocity usually describes a vector rather than simply a scalar speed.
Definitions Since the thermal velocity is only a "typical" velocity, a number of different definitions can be and are used. Taking k B {\displaystyle k_{\text{B}}} to be the Boltzmann constant, T {\displaystyle T} the absolute temperature, and m {\displaystyle m} the mass of a particle, we can write the different thermal velocities:
In one dimension If v th {\displaystyle v_{\text{th}}} is defined as the root mean square of the velocity in any one dimension (i.e. any single direction), then
v th = k B T m . {\displaystyle v_{\text{th}}={\sqrt {\frac {k_{\text{B}}T}{m}}}.}
If v th {\displaystyle v_{\text{th}}} is defined as the mean of the magnitude of the velocity in any one dimension (i.e. any single direction), then
v th = 2 k B T π m . {\displaystyle v_{\text{th}}={\sqrt {\frac {2k_{\text{B}}T}{\pi m}}}.}
In three dimensions If v th {\displaystyle v_{\text{th}}} is defined as the most probable speed, then
v th = 2 k B T m . {\displaystyle v_{\text{th}}={\sqrt {\frac {2k_{\text{B}}T}{m}}}.}
If v th {\displaystyle v_{\text{th}}} is defined as the root mean square of the total velocity, then
v th = 3 k B T m . {\displaystyle v_{\text{th}}={\sqrt {\frac {3k_{\text{B}}T}{m}}}.}
If v th {\displaystyle v_{\text{th}}} is defined as the mean of the magnitude of the velocity of the atoms or molecules, then
v th = 8 k B T π m . {\displaystyle v_{\text{th}}={\sqrt {\frac {8k_{\text{B}}T}{\pi m}}}.}
All of these definitions are in the range
v th = ( 1.6 ± 0.2 ) k B T m . {\displaystyle v_{\text{th}}=(1.6\pm 0.2){\sqrt {\frac {k_{\text{B}}T}{m}}}.}
Thermal velocity at room temperature At 20 °C (293.15 kelvins), the mean thermal velocity of common gasses in three dimensions is:
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