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Thermoplastic

Thermoplastic is a engineering topic covered in the lgStudy science library. This page brings together a partial reference excerpt, illustrations, worked examples, real-world applications and a short study plan, so you can understand Thermoplastic rather than just read about it. In short: A thermoplastic, or thermosoftening plastic, is any plastic polymer material that becomes pliable or moldable at a certain elevated temperature and solidifies upon cooling. Most thermoplastics have a high molecular weight.

Thermoplastic — main illustration
Thermoplastic — illustration

Key takeaways

  • Thermoplastic belongs to engineering; place it in that map before memorising details.
  • Learn the definition first, then one example that makes the definition concrete.
  • Connect Thermoplastic to a quantity you can measure, compute or draw — that is where exam questions come from.
  • Reproduce the core statement of Thermoplastic from memory before moving on to harder problems.

Reference excerpt

A thermoplastic, or thermosoftening plastic, is any plastic polymer material that becomes pliable or moldable at a certain elevated temperature and solidifies upon cooling. Most thermoplastics have a high molecular weight. The polymer chains associate by intermolecular forces, which weaken rapidly with increased temperature, yielding a viscous liquid. In this state, thermoplastics may be reshaped, and are typically used to produce parts by various polymer processing techniques such as injection molding, compression molding, calendering, and extrusion. Thermoplastics differ from thermosetting polymers (or "thermosets"), which form irreversible chemical bonds during the curing process. Thermosets do not melt when heated, but typically decompose and do not reform upon cooling.

Above its glass transition temperature and below its melting point, the physical properties of a thermoplastic change drastically without an associated phase change. Some thermoplastics do not fully crystallize below the glass transition temperature, retaining some or all of their amorphous characteristics. Amorphous and semi-amorphous plastics are used when high optical clarity is necessary, as light is scattered strongly by crystallites larger than its wavelength. Amorphous and semi-amorphous plastics are less resistant to chemical attack and environmental stress cracking because they lack a crystalline structure. Brittleness can be decreased with the addition of plasticizers, which increases the mobility of amorphous chain segments to effectively lower the glass transition temperature. Modification of the polymer through copolymerization or through the addition of non-reactive side chains to monomers before polymerization can also lower it. Before these techniques were employed, plastic automobile parts would often crack when exposed to cold temperatures. These are linear or slightly branched long chain molecules capable of repeatedly softening on heating and hardening on cooling.

Acrylic Today's acrylics industry can be divided into two distinct multibillion-dollar markets: the polyacrylic acids (PAA) and its ester derivatives (PAc) market, and the poly(methyl methacrylate) (PMMA) market. PMMA is also known by trade names such as Lucite, Perspex and Plexiglas. It serves as a sturdy substitute for glass for items such as aquariums, buttons, motorcycle helmet visors, aircraft windows, viewing ports of submersibles, and lenses of exterior lights of automobiles. It is extensively used to make signs, including lettering and logos. In medicine, it is used in bone cement and to replace eye lenses. Acrylic paint consists of PMMA particles suspended in water. For many decades, PMMA has been the predominant methacrylic ester produced worldwide. Major players in the PMMA market are Mitsubishi Rayon (Japan), Arkema SA (France), LG MMA (South Korea), Chi Mei Corp. (Taiwan), Sumimoto Chemical Company Ltd (Japan), Evonik Industries (Germany), BASF (Germany), Dow Chemical Company (U.S.), AkzoNobel (The Netherlands), Quinn Plastics (UK) and Cytec Industries (U.S.). Regarding the PAA and PAc market, key manufacturers are Nippon Shokubai Company Ltd. (Japan), Arkema SA (France) and Dow Chemical Company (U.S.).

ABS Acrylonitrile butadiene styrene (ABS) is a terpolymer synthesized from styrene and acrylonitrile in the presence of polybutadiene, resulting in a long chain of polybutadiene crisscrossed with shorter chains of poly(styrene-co-acrylonitrile). ABS is a light-weight material that exhibits high impact resistance and mechanical toughness. It poses few risks to human health under normal handling. It is used in many consumer products, such as toys, appliances, and telephones.

Nylon Nylon belongs to a class of polymers called polyamides. It has served as a substitute mainly for hemp, cotton and silk, in products such as parachutes, cords, sails, flak vests and clothing. Nylon fibres are useful in making fabrics, rope, carpets and musical strings. In bulk form, nylon is used for mechanical parts including machine screws, gears and power tool casings. In addition, it is used in the manufacture of heat-resistant composite materials.

PLA Polylactic acid (polylactide) is a compostable thermoplastic aliphatic polyester derived from renewable resources, such as corn starch (in the United States), sugar beet pulp (in Europe), tapioca roots, chips or starch (mostly in Asia), or sugarcane. It is the most common material used for 3D printing with fused deposition modeling techniques.

Polybenzimidazole Polybenzimidazole (Poly-[2,2'-(m-phenylen)-5,5'-bisbenzimidazole], PBI) fiber is a synthetic fiber with a very high melting point. It has exceptional thermal and chemical stability and does not readily ignite. It was first discovered by American polymer chemist Carl Shipp Marvel in the pursuit of new materials with superior stability, retention of stiffness, and toughness at elevated temperatures. Due to its high stability, polybenzimidazole is used to fabricate high-performance protective apparel such as firefighter's gear, astronaut space suits, high temperature protective gloves, welders' apparel and aircraft wall fabrics. In recent years, polybenzimidazole found its application as membrane in fuel cells.

Polycarbonate Polycarbonate (PC) thermoplastics are known under trademarks such as Lexan, Makrolon, Makroclear, and arcoPlus. They are easily worked, molded, and thermoformed for many applications, such as electronic components, construction materials, data storage devices, automotive and aircraft parts, check sockets in prosthetics, and security glazing. Polycarbonates do not have a unique resin identification code. Items made from polycarbonate can contain the precursor monomer bisphenol A (BPA). Susceptible to UV light, exposure results in yellowing. Degradation is especially visible in headlamps that lost or didn't have proper protective coating.

Polyether sulfone Polyether sulfone (PES) or polysulfone is a class of specially engineered thermoplastics with high thermal, oxidative, and hydrolytic stability, and good resistance to aqueous mineral acids, alkalis, salt solutions, oils and greases.

… excerpt ends here. Continue reading the full article.

Illustrations

Thermoplastic: Stress-strain graph of a thermoplastic material
Stress-strain graph of a thermoplastic material

Worked examples

Example 1 — a first encounter with Thermoplastic

Start with the simplest possible case. Write down what Thermoplastic claims or describes in one sentence, then invent the smallest concrete situation in which that sentence is true. In engineering, the smallest case is usually a single object, a single equation or a single measurement. Check that every symbol or term in your sentence has a meaning in that case.

Example 2 — changing one variable

Take the situation from Example 1 and change exactly one quantity: double it, halve it, or set it to zero. Predict what should happen to Thermoplastic before you calculate. Comparing your prediction with the result is the fastest way to find out whether you understand the idea or only the words.

Example 3 — an exam-style question

Typical questions about Thermoplastic ask you to (a) state it precisely, (b) apply it to given data, and (c) explain a limitation. Practise writing all three answers in under five minutes; the third part is what separates a full-mark answer from an average one.

Applications of Thermoplastic

In research
Thermoplastic appears in engineering research whenever the underlying quantities have to be modelled precisely. Papers usually cite it as a starting assumption and then explore where it breaks down.
In technology and industry
Engineering practice reuses Thermoplastic in design rules, simulations and safety margins. Knowing the idea lets you read a specification sheet and understand why the numbers look the way they do.
In the classroom
Thermoplastic is common in secondary-school and first-year university syllabi. It links to neighbouring topics Roofing materials, Thermoplastics, so understanding it makes those chapters shorter.
In everyday life
Look for Thermoplastic outside the textbook — in sport, cooking, traffic, electronics or the sky above you. An example you found yourself is remembered far longer than one you were given.
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How to study Thermoplastic in 20 minutes

  1. Read the reference excerpt below once, without taking notes.
  2. Close the page and write down what Thermoplastic means in your own words.
  3. Compare your version with the excerpt and mark what you missed.
  4. Work through the three examples above with pen and paper.
  5. Explain Thermoplastic out loud to somebody else — or to Teacher Smith in the lgStudy chat.

Frequently asked questions

What is Thermoplastic in simple terms?

A thermoplastic, or thermosoftening plastic, is any plastic polymer material that becomes pliable or moldable at a certain elevated temperature and solidifies upon cooling. Most thermoplastics have a high molecular weight.

Why does Thermoplastic matter?

Because it connects several engineering ideas at once: it gives you a definition you can apply, a quantity you can calculate, and a way to check whether a result is plausible.

How should I study Thermoplastic?

Read the excerpt, restate it from memory, then work through the examples and applications listed on this page. The five-step study plan above takes about twenty minutes.

What does this page cover?

It gives you a compact reference excerpt plus original lgStudy explanations, examples, applications and study material on Thermoplastic.

Tags

  • Roofing materials
  • Thermoplastics

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