Thiocyanuric acid is the organosulfur compound with the formula (HNC=S)3. It is analogous to cyanuric acid ((HNC=O)3). Cyanuric acid is white whereas thiocyanuric acid is yellow. It can also be viewed as a trimeric thioamide.
Structure It is a planar molecular as determined by X-ray crystallography. Like cyanuric acid, thiocyanuric acid forms extended hydrogen-bonded network resulting in a sheet-like structure. This arrangement is relevant to the high melting point of the compound.
Synthesis, reactions, applications Thiocyanuric acid precipitates from warm, acidic solutions of thiocyanic acid. A modern synthesis begins instead with a preformed ring: cyanuric chloride reacts with sodium hydrosulfide to give table salt and thiocyanuric acid. The compound is mildly acidic, with pKa's of 5.7, 8.4, and 11.4. Various salts of (HNC=S)−3 have been characterized. The compound has an affinity for heavy metals. This attribute has been exploited by applying thiocyanuric acid and derivatives to treatment of waste waters.
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