Thiuram monosulfides are a class of organosulfur compounds with the formula (R2NCS)2S (R = organic group). Many examples are known, but popular ones include R = Me and R = Et. They are typically yellow solids that are soluble in polar organic solvents.
Structure, synthesis Thiuram monosulfides feature a pair planar thioamide subunits linked by a sulfur atom. Thiuram monosulfides can be prepared by desulfurization of thiuram disulfides Treatment of a thiuram disulfide with triphenylphosphine, or with cyanide salts, yields the corresponding thiuram sulfide:
(R2NC(S)S)2 + PPh3 → (R2NCS)2S + S=PPh3 (Ph = C6H5)
References

![Thiuram monosulfides: structure of tetramethylthiuram monosulfide. The C=S and C-S distances are 166, 179 picometers. Color code: yellow = S, blue = N.[1]](https://upload.wikimedia.org/wikipedia/commons/thumb/2/24/CSD_CIF_TMTURS.png/500px-CSD_CIF_TMTURS.png?utm_source=en.wikipedia.org&utm_campaign=parser&utm_content=thumbnail)
