Thorium diiodide is an iodide of thorium, with the chemical formula of ThI2. It is an electride with the ionic formula Th4+(I−)2e−2. It is air-sensitive.
Preparation Thorium diiodide cn be prepared by heating thorium tetraiodide in stoichiometric amounts of thorium:
ThI4 + Th → 2 ThI2 It can also be prepared by directly reacting thorium and iodine:
Th + I2 → ThI2 Thorium diiodide can also be prepared from the decomposition of thorium triiodide at temperatures above 550 °C:
2 ThI3 → ThI4 + ThI2
Properties Like the diiodides of cerium, praseodymium and gadolinium, it has a metallic gold lustre and high electrical conductivity.
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