Thulium(III) sulfate is an inorganic compound of thulium, with the molecular formula Tm2(SO4)3. It has received little scientific attention as its solubility in water was only determined in 2023 despite the compound being known since at least 1911.
Preparation Thulium(III) oxide has been reported to react with strong acids with hydrochloric acid being explicitly mentioned. Sulfuric acid is also a strong acid that forms sulfate salts.
Tm2O3 + 3 H2SO4 → Tm2(SO4)3 + 3 H2O
Properties Thulium sulfate can form an octahydrate. It can also be used as a dopant for e.g. lithium borate glass that contains copper nanoparticles in order to limit photo-darkening or in thermoluminescent dosimeters. It undergoes ion exchange with barium bromate to yield thulium(III) bromate and barium sulfate which precipitates from the aqueous solution.
Tm2(SO4)3 + 3 Ba(BrO3)2 → 2 Tm(BrO3)3 + 3 BaSO4↓
References



