Tin(IV) iodide, also known as stannic iodide, is the chemical compound with the formula SnI4. This tetrahedral molecule crystallizes as a bright orange solid that dissolves readily in nonpolar solvents such as benzene.
Preparation The compound is usually prepared by the reaction of tin and iodine:
Sn + 2 I2 → SnI4
Chemical properties The compound hydrolyses in water. In hydroiodic acid, it reacts to form a rare example of a hexaiodometallate (here hexaiodostannate(IV)):
SnI4 + 2 I− → [SnI6]2−
Physical properties Tin(IV) iodide is an orange solid under standard conditions. It has a cubic crystal structure with the space group Pa3 (space group no. 205), the lattice parameter a = 1226 pm and eight formula units per unit cell. This corresponds approximately to a cubic close packing of iodine atoms in which 1/8 of all tetrahedral gaps are occupied by tin atoms. This leads to discrete tetrahedral SnI4 molecules.
See also Tin(II) iodide Tin(IV) chloride
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