Titanium powder metallurgy offers the possibility of creating net-shape or near-net-shape parts without the material loss and cost associated with having to machine intricate components from wrought billet. Powders can be produced by the blended elemental technique or by pre-alloying and then consolidation by metal injection moulding, hot isostatic pressing, direct powder rolling, or laser-engineered net shaping. Titanium powder is used in aerospace, medical implants, 3D printing, powder metallurgy, and surface coatings due to its strength, low weight, and corrosion resistance. It also plays a vital role in energy generation, in sports equipment, and as a catalyst in chemical processes.
Blended elemental technique The traditional technique of titanium production is via the Kroll process, which involves chlorination of TiO2 ore in the presence of carbon and reacting the resulting TiCl4 with magnesium to produce titanium sponge. These processes take place at temperatures as high as 1040 °C. The sponge particles range in size from 45 to 180 μm, with particles ~150 μm termed "sponge fines". These fines are irregularly shaped and porous with a sponge-like morphology. The fines are then blended with alloy additions, cold-compacted into a green compact at up to 415 MPa, then vacuum-sintered at 1260 °C to produce a 99.5% dense component. Hot isostatic pressing (HIP) can further increase the density of these parts and produce components more economically than cast or wrought parts, but the porosity present in the material degrades fatigue and fracture properties. The blended-elemental approach has been used to produce valves for the Toyota Altezza, golf-club heads, and softball bats. More recently, close-to-100% dense Ti Grade 5 parts have been achieved using a hydrided powder along with 60:40 Al:V master alloy. The mechanical properties compare well with those exhibited by cast-and-wrought products. A cost estimate of less than $3.00 for a 0.320-gram automotive connection link has been made.
Pre-alloyed powder production Several techniques exist to produce pre-alloyed powder, such as Grade 5. In the hydride-dehydride process, feedstock such as solid scrap, billet, or machined turnings are processed to remove contaminants, hydrogenated to produce brittle material, then ground under argon in a vibratory ball mill, typically at 400 °C for 4 hours at a pressure of 1 psi for Ti Grade 5. The resulting particles are angular and measure between 50 and 300 μm. Cold compaction after dehydrogenation of the powder, followed by either vacuum hot pressing (in this case the dehydrogenation process can be bypassed as hydrogen is removed under vacuum) or HIP and a final vacuum anneal, produces powders with hydrogen below 125 ppm. The possible presence of contaminants makes these powders unsuitable for use in critical aircraft applications. In the plasma rotating electrode process (PREP), the feedstock, such as Ti Grade 5, is in the form of a rotating bar which is arced with gas plasma. The molten metal is centrifugally flung off the bar, cools down, and is collected. The powders produced are spherical, between 100 and 300 μm in size, with good packing and flow characteristics, making the powder ideal for high-quality, near-net-shape parts produced by HIP, such as aviation parts and porous coatings on hip prostheses. In the titanium gas atomisation (TGA) process, titanium is vacuum-induction-skull melted in a water-cooled copper crucible, the metal tapped, and the molten metal stream atomized with a stream of high-pressure inert gas. The tiny droplets are spherical and measure between 50 and 350 μm. The TGA process has been used to produce a wide variety of materials, such as commercially pure titanium, conventional alpha-beta, and beta alloys. In plasma atomization (PA) process, a titanium wire is atomized by 3 inert-gas plasma jets to form spherical metal powders. The distribution of diameter obtained in the PA process ranges from 0 to 200 μm, and the powders obtained are very pure. The PA process specializes in the production of high-melting-point material as titanium (CP-Ti, Ti-6Al-4V), niobium, molybdenum, tantalum, and many more.
Electrode induction-melting gas atomization In the electrode induction-melting gas atomization (EIGA) process, a pre-alloyed titanium electrode bar is slowly rotated and fed through an induction coil, where the tip is melted without contacting any crucible material. The molten metal drips directly into a high-pressure inert gas stream (argon or helium), producing highly spherical powder typically in the 20–150 μm range. Because no ceramic crucible is used, EIGA minimises the oxygen pickup that can occur when reactive titanium alloys contact refractory materials during conventional gas atomisation.
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