Concrete

Concrete is a composite material composed of aggregate bound together with a fluid cement that cures to a solid. It is the second-most-used substance (after water), the most widely used building material, and the most-manufactured material in the world. Cement-bound concrete differs from the less rigid, less durable asphaltic concrete, which has a bituminous binder. When aggregate is mixed with dry Portland cement and water, the mixture forms a fluid slurry that can be poured and molded into shape. The cement reacts with the water through a process called hydration, which hardens it after several hours to form a solid matrix that binds the materials together into a durable stone-like material with various uses. This time allows concrete to not only be cast in forms, but also to have a variety of tooled processes performed. The hydration process is exothermic, which means that ambient temperature plays a significant role in how long it takes concrete to set. Often, additives (such as pozzolans or superplasticizers) are included in the mixture to improve the physical properties of the wet mix, delay or accelerate the curing time, or otherwise modify the finished material. Most structural concrete is poured with reinforcing materials (such as steel rebar) embedded to provide tensile strength, yielding reinforced concrete. Before the invention of Portland cement in the early 1800s, lime-based cement binders, such as lime putty, were often used. The overwhelming majority of concretes are produced using Portland cement, but sometimes with other hydraulic cements, such as calcium aluminate cement. Many other non-cementitious types of concrete exist with other methods of binding aggregate together, including asphalt concrete with a bitumen binder, which is frequently used for road surfaces, and polymer concretes that use polymers as a binder. Concrete is distinct from mortar. Whereas concrete is itself a building material, and contains both coarse (large) and fine (small) aggregate particles, mortar contains only fine aggregates and is mainly used as a bonding agent to hold bricks, tiles and other masonry units together. Grout is another material associated with concrete and cement. It also does not contain coarse aggregates and is usually either pourable or thixotropic, and is used to fill gaps between masonry components or coarse aggregate which has already been put in place. Some methods of concrete manufacture and repair involve pumping grout into the gaps to make up a solid mass in situ.

Etymology The word concrete comes from the Latin word "concretus" (meaning compact or condensed), the perfect passive participle of "concrescere", from "con-" (together) and "crescere" (to grow).

History

Ancient times Concrete floors were found in the royal palace of Tiryns, Greece, which dates roughly to 1400 to 1200 BC. Lime mortars were used in Greece, such as in Crete and Cyprus, in 800 BC. The Assyrian Jerwan Aqueduct (688 BC) made use of waterproof concrete. Concrete was used for construction in many ancient structures. Small-scale production of concrete-like materials was pioneered by the Nabatean traders who occupied and controlled a series of oases and developed a small empire in the regions of southern Syria and northern Jordan from the 4th century BC. They discovered the advantages of hydraulic lime, with some self-cementing properties, by 700 BC. They built kilns to supply mortar for the construction of rubble masonry houses, concrete floors, and underground waterproof cisterns. They kept the cisterns secret as these enabled the Nabataeans to thrive in the desert. Some of these structures survive to this day.

Classical era

The Romans used concrete extensively from 300 BC to AD 476. During the Roman Empire, Roman concrete (or opus caementicium) was made from quicklime, pozzolana, and an aggregate of pumice. Its widespread use in many Roman structures, a key event in the history of architecture termed the Roman architectural revolution, freed Roman construction from the restrictions of stone and brick materials. It enabled revolutionary new designs in terms of both structural complexity and dimension. The Colosseum in Rome was built largely of concrete. The Pantheon has the world's largest unreinforced concrete dome.

Concrete, as the Romans knew it, was a new and revolutionary material. Laid in the shape of arches, vaults, and domes, it quickly hardened into a rigid mass, free from many of the internal thrusts and strains that troubled the builders of similar structures in stone or brick. Modern tests show that opus caementicium had a similar compressive strength to modern Portland-cement concrete (c. 200 kg/cm2 [20 MPa; 2,800 psi]), however, due to the absence of reinforcement, its tensile strength was far lower than modern reinforced concrete, and its mode of application also differed:

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