Trichlorostannate is the inorganic anion with the formula SnCl−3. It is the chloride adduct of stannous chloride:
SnCl2 + Cl− → SnCl−3 The trichlorostannate anion is pyramidal in shape, being similar to trichlorogermanate (GeCl−3) and antimony trichloride. The anion can be isolated as quaternary ammonium salt and cesium salts. The compound with the formula K2SnCl4·H2O is a hydrated double salt, consisting of SnCl−3 and Cl−.
Trichlorostannate serves as a ligand in coordination chemistry, illustrated by the complex [Pt(SnCl3)5]3−.
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![Trichlorostannate: [Pt(SnCl3)5]3-. Color code: green = Cl, gray = Sn, blue = Pt.](https://upload.wikimedia.org/wikipedia/commons/thumb/2/2c/CSD_CIF_BENLUB.png/500px-CSD_CIF_BENLUB.png?utm_source=en.wikipedia.org&utm_campaign=parser&utm_content=thumbnail)
