Triiodine fluorosulfate is the inorganic compound with the chemical formula I3SO3F. It is the fluorosulfate (SO3F−) salt of the I+3 polyhalogen ion.
Synthesis Triiodine fluorosulfonate is obtained from iodine and iodine(I) fluorosulfonate at 85 °C.
I2 + ISO3F → I3SO3F Also, a reaction of iodine with peroxydisulfuryl difluoride:
3I2 + S2O6F2 → 2I3SO3F
Chemical characteristics The compound hydrolyzes well in water and dissolves in sulfuric acid. It reacts with tetrafluoroethylene (C2F4) to form ICF2CF2O3SF and I2.
See also Bromine fluorosulfate Chlorine fluorosulfate Iodine fluorosulfate
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