Triphenylphosphine dibromide is the organophosphorus compound with the formula (C6H5)3PBr2. It is a white or colorless hygroscopic solid that is used as a brominating agent in organic synthesis. It is prepared by the addition of bromine to triphenylphosphine in an inert solvent. Often it is generated in situ. Triphenylphosphine dibromide is usually depicted as a phosphonium salt with tetrahedral phosphorus cation. According to X-ray crystallography, solid structures can feature halogen bonding. Illustrative of its use is the conversion of 2-naphthol to 2-bromonaphthalene:
C10H7(OH) + (C6H5)3PBr2 → C10H7Br + (C6H5)3PO + HBr
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