UPt3 is an inorganic binary intermetallic crystalline compound of platinum and uranium.
Production It can be synthesised as an intermetallic compound, by direct fusion of pure components at 1700 °C according to stoichiometric calculations:
3 Pt + U → UPt3 It can also be synthesised by reduction of uranium dioxide with hydrogen in the presence of platinum at 1700 °C:
UO2 + 2 H2 + 3 Pt → UPt3 + 2 H2O
Physical properties UPt3 forms crystals of hexagonal symmetry (some studies hypothesize a trigonal structure instead), space group P63/mmc, cell parameters a = 0.5766 nm and c = 0.4898 nm (c should be understood as distance from planes), with a structure similar to nisnite (Ni3Sn) and MgCd3. The compound congruently melts at 1700 °C. The enthalpy of formation of the compound is -111 kJ/mol. At temperatures below 1 K it becomes superconducting. Due to the large effective mass of the conduction electrons, UPt3 is classed as a Heavy fermion superconductor.
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