Unpolarized light is light with a random, time-varying polarization. Natural light, like most other common sources of visible light, is produced independently by a large number of atoms or molecules whose emissions are uncorrelated. Unpolarized light can be produced from the incoherent combination of vertical and horizontal linearly polarized light, or right- and left-handed circularly polarized light. Conversely, the two constituent linearly polarized states of unpolarized light cannot form an interference pattern, even if rotated into alignment (Fresnel–Arago 3rd law). A so-called depolarizer acts on a polarized beam to create one in which the polarization varies so rapidly across the beam that it may be ignored in the intended applications. Conversely, a polarizer acts on an unpolarized beam or arbitrarily polarized beam to create one which is polarized. Unpolarized light can be described as a mixture of two independent oppositely polarized streams, each with half the intensity. Light is said to be partially polarized when there is more power in one of these streams than the other. At any particular wavelength, partially polarized light can be statistically described as the superposition of a completely unpolarized component and a completely polarized one. One may then describe the light in terms of the degree of polarization and the parameters of the polarized component. That polarized component can be described in terms of a Jones vector or polarization ellipse. However, in order to also describe the degree of polarization, one normally employs Stokes parameters to specify a state of partial polarization.
Motivation The transmission of plane waves through a homogeneous medium are fully described in terms of Jones vectors and 2×2 Jones matrices. However, in practice there are cases in which all of the light cannot be viewed in such a simple manner due to spatial inhomogeneities or the presence of mutually incoherent waves. So-called depolarization, for instance, cannot be described using Jones matrices. For these cases it is usual instead to use a 4×4 matrix that acts upon the Stokes 4-vector. Such matrices were first used by Paul Soleillet in 1929, although they have come to be known as Mueller matrices. While every Jones matrix has a Mueller matrix, the reverse is not true. Mueller matrices are then used to describe the observed polarization effects of the scattering of waves from complex surfaces or ensembles of particles, as shall now be presented.
Coherency matrix The Jones vector perfectly describes the state of polarization and phase of a single monochromatic wave, representing a pure state of polarization as described above. However any mixture of waves of different polarizations (or even of different frequencies) do not correspond to a Jones vector. In so-called partially polarized radiation the fields are stochastic, and the variations and correlations between components of the electric field can only be described statistically. One such representation is the coherency matrix:
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