Uranium(IV) hydride is a chemical compound of uranium and hydrogen with the chemical formula UH4, a metal hydride.
Synthesis and Reactions In 1997, Souter et al. reported the production of UH4 by reacting laser ablated uranium atoms with dihydrogen and capturing the product on solid argon. The assignment of the structure was made using infrared spectroscopic evidence supported by DFT calculations. Uranium(IV) hydride has a quasi-tetrahedral (Cs) structure and is formed by the successive insertion of uranium into two hydrogen molecules:
U + H2 → UH2 UH2 + H2 → UH4 Further reaction with hydrogen only produces dihydrogen complexes: UH4(H2)n (1 ≤ n ≤ 6).
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