Volcanogenic massive sulfide ore deposit

Volcanogenic massive sulfide ore deposits, also known as VMS ore deposits, are a type of metal sulfide ore deposit, mainly copper-zinc which are associated with and produced by volcanic-associated hydrothermal vents in submarine environments. These deposits are also sometimes called volcanic-hosted massive sulfide (VHMS) deposits. The density generally is 4500 kg/m3. They are predominantly stratiform accumulations of sulfide minerals that precipitate from hydrothermal fluids on or below the seafloor in a wide range of ancient and modern geological settings. In modern oceans they are synonymous with sulfurous plumes called black smokers. They occur within environments dominated by volcanic or volcanic derived (e.g., volcano-sedimentary) rocks, and the deposits are coeval and coincident with the formation of said volcanic rocks. As a class, they represent a significant source of the world's copper, zinc, lead, gold and silver ores, with cobalt, tin, barium, sulfur, selenium, manganese, cadmium, indium, bismuth, tellurium, gallium and germanium as co- or by-products. Volcanogenic massive sulfide deposits are forming today on the seafloor around undersea volcanoes along many mid ocean ridges, and within back-arc basins and forearc rifts. Mineral exploration companies are exploring for seafloor massive sulfide deposits; however, most exploration is concentrated in the search for land-based equivalents of these deposits. The close association with volcanic rocks and eruptive centers sets VMS deposits apart from similar ore deposit types which share similar source, transport and trap processes. Volcanogenic massive sulfide deposits are distinctive in that ore deposits are formed in close temporal association with submarine volcanism and are formed by hydrothermal circulation and exhalation of sulfides which are independent of sedimentary processes, which sets VMS deposits apart from sedimentary exhalative (SEDEX) deposits. There is a subclass of VMS deposits, the volcanic- and sediment-hosted massive sulfide (VSHMS) deposits, that do share characteristics that are hybrid between the VMS and SEDEX deposits. Notable examples of this class include the deposits of the Bathurst Mining Camp, New Brunswick, Canada (e.g., Brunswick #12); the deposits of the Iberian Pyrite Belt, Portugal and Spain, and the Wolverine deposit, Yukon, Canada.

Genetic model The source of metal and sulfur in VMS deposits is a combination of incompatible elements which are leached from the volcanic pile in the sub-seafloor hydrothermal alteration zone by hydrothermal circulation. Hydrothermal circulation is generally considered to be driven via heat in the crust often related to deep-seated gabbro intrusions. Transport of metals occurs via convection of hydrothermal fluids, the heat for this supplied by the magma chamber which sits below the volcanic edifice. Cool ocean water is drawn into the hydrothermal zone and is heated by the volcanic rock and is then expelled into the ocean, the process enriching the hydrothermal fluid in sulfur and metal ions. The ore materials are trapped within a fumarole field or a black smoker field when they are expelled into the ocean, cool, and precipitate sulfide minerals as stratiform sulfide ore. Some deposits show evidence of formation via deposition of sulfide via replacement of altered volcanosedimentary rocks and may also form by invasion of sulfur-rich brines into unconsolidated sediments.

Geology The typical location for VMS deposits is at the top of the felsic volcanic sequence, within a sequence of volcaniclastic tuffaceous epiclastics, cherts, sediments or perhaps fine tuffs which are usually related to the underlying volcanics. The hangingwall to the deposit is broadly related to a more mafic sequence of volcanic rocks, either andesite (examples being Whim Creek & Mons Cupri, Western Australia or Millenbach, Canada), or basalt (Hellyer, Tasmania) or absent or sediments only (Kangaroo Caves, Western Australia). VMS deposits are associated spatially and temporally with felsic volcanic rocks, usually present in the stratigraphy below the deposit and often as the direct footwall to the deposit. Sediments are usually contiguous with VMS deposits in some form or another and typically are present as (manganiferous) cherts and chemical sediments deposited within a submarine environment. The hanging wall to the deposit can be volcanic units essentially contiguous and coeval with the footwall rocks, indicating mineralisation was developed during an inter-eruptive pause. In bimodal volcanic subtypes, it may be volcanic rock dissimilar to the footwall volcanics or sedimentary strata if mineralisation occurred toward the end of an eruptive cycle. Hybrid VMS-SEDEX deposits of the siliciclastic associations (see below) may be developed within interflow sediments or within units of sedimentary rocks which are present discontinuously throughout a larger and essentially contiguous volcanic package. Altogether, these geological features have been interpreted to show an association of VMS deposits with hydrothermal systems developed above or around submarine volcanic centres.

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