Volynskite (Russian: Волынски́т), is a rare hydrothermal mineral of the sulfide class (the matildite group), that forms microscopic grains in related minerals, which in composition is a complex bismuth-silver telluride with the calculated formula AgBiTe2. Volynskite was first discovered and identified between 1960 and 1965 by Marianna Bezsmertnaya and Lada Soboleva who observed thin sections among closely related tellurides in the territory of the Zod gold deposit. It was named in honor of the late professor of mineralogy and head of the mineralogy department at the Institute of Mineralogy, Geochemistry and Crystal Chemistry of Rare Elements, Igor Volynsky, who had died suddenly in September 1962.
Discovery history and name For the first time, a new previously unknown mineral (the future volynskite) was encountered by M. S. Bezsmertnaya and Sh. O. Amirayan during a microscopic study of samples from the Sotk gold mine and was initially mistaken for wehrlite. In the course of further research conducted in 1960–1963, it was established that, based on a combination of chemical, X-ray, and optical characteristics, this mineral differs from all natural tellurium compounds described in the literature and represents a new, independent mineral species. After three years of hard work, Marianna Bezsmertnaya recalled the first steps in identifying the new mineral: “During a microscopic study of ores from gold deposits in Armenia, M.S. Bezsmertnaya and Sh.O. Amiryan encountered a mineral in the telluride association that differed little in optical properties from tellurobismuthite, with which it was closely intergrown in the form of microscopically small inclusions. Based on optical features and qualitative chemical composition, the mineral was initially mistaken for wehrlite (pilsenite). However, the results of our subsequent detailed studies of the chemical composition, crystallographic and optical properties showed that the mineral encountered was previously unknown and had not been described by anyone.” In 1960, when the composition of the mineral had not yet been precisely determined, studies were conducted using the local microspectral analysis method using N. V. Korolev's setup. The future volynskite was removed on one plate with tellurobismuthite, which was closely intergrown with it, and the analysis conditions for both minerals were identical. The closeness of the elemental composition of volynskite to tellurobismuthite made it possible to at least approximately estimate the content of individual elements in it.[9] Based on the results of microsample analysis, it was established that the main elements included in the composition of volynskite are silver, bismuth, and tellurium. In the same 1960, similar studies were conducted by Z. M. Sverdlov on a microspectral setup at A.P. Karpinsky Russian Geological Research Institute (VSEGEI). The same elements were identified in the composition of the new mineral. A year later, at the personal request of Marianna Bezsmertnaya, a more detailed quantitative microspectral analysis of the future volynskite was conducted by N. V. Korolev at the State Optical Institute in Leningrad. Two closely related tellurides were used as standards for calculating the mineral formula: tellurobismuthite (Bi2Te3) and hessite (Ag2Te). Before filing an application for registration of the new mineral, a total of 11 microspectral and 7 X-ray analyses were conducted. Based on the results of the study, the formula of volynskite was finally established as AgBiTe2, close within the error limits to the synthetic compound AgBiTe2. In 1962, also at the request of researchers, an artificial compound of the composition AgBiTe2 was synthesized by A. Yu. Malevsky in the experimental laboratory of IMGRE from stoichiometric quantities of its three constituent elements. The synthesis was carried out for five hours at temperatures of 1000-1400 °C, followed by quenching for one and a half hours from 400° in an open furnace with free access to air. According to the chemical composition, optical and X-ray data, a fundamental similarity was noted between the low-temperature modification of AgBiTe2 obtained at the Institute of Semiconductors, the main phase of the compound synthesized by A. Yu. Malevsky and the mineral under study. Specific difficulties in studying the new mineral were primarily related to the lack of any massive samples that would allow determination using qualitative analysis. As a result, the authors of the future discovery repeatedly checked and rechecked the results obtained using different methods.
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