William Houlder Zachariasen (5 February 1906 – 24 December 1979), more often known as W. H. Zachariasen, was a Norwegian-American physicist, specializing in X-ray crystallography and famous for his work on the structure of glass.
Background Zachariasen was born in Langesund at Bamble in Telemark, Norway. He entered the University of Oslo in 1923, where he studied in the Mineralogical Institute. Zachariasen published his first article in 1925 when he was 19 years old, after having presented the contents of the article to the Norwegian Academy of Sciences in the preceding year. Over a span of 55 years he published over 200 scientific papers, many of which he was the sole author. In 1928 at the age of 22 he earned his PhD from the University of Oslo, becoming the youngest person ever to receive a PhD in Norway. His thesis advisor was the geochemist Victor Moritz Goldschmidt. In the years 1928–1929, as a postdoctoral fellow at Manchester University in the laboratory of Lawrence Bragg, Zachariasen began his studies on the physical structure of silicates. His work led to the first real understanding of the structure of glass. He returned to the University of Oslo but, within a year, accepted an offer from the Nobel laureate Arthur Compton.
Career In 1930 Zachariasen, at the age of 24, became a member of the faculty of physics at the University of Chicago. In 1935–1936 he was a Guggenheim Fellow. In 1941 Zachariasen became an American citizen and then, from 1943 to 1945, worked on the Manhattan Project. In 1945 he published his important monograph Theory of X-ray Diffraction in Crystals. In 1948–1949 he published 29 papers. From 1945 to 1950 and again from 1955 to 1959 Zachariasen was the chair of the physics department at the University of Chicago. In 1963 Zachariasen examined a well-known discrepancy between the calculated and measured intensities of diffraction X-ray beams by making careful measurements of diffraction intensities from a target consisting of the mineral Hambergite. Using his experiment data, he reconsidered the prevailing widely accepted and extensively used theory. In a paper published in 1963, he showed that C. G. Darwin's formula for the secondary extinction correction contained an error in the treatment of the polarization of the X-ray beams. In 1967 Zachariasen published a general theory of X-ray diffraction in crystals that gave more precise estimates for X-diffraction intensities. In 1968 he published a theory that took into account both extinction and the Borrmann effect for X-ray diffraction in mosaic crystals.
Personal life In 1930, before leaving Norway, Zachariasen married Ragni Durban-Hansen, granddaughter of the geologist W. C. Brøgger. The Zachariasens had two children, Fredrik and Ellen. As a couple, the Zachariasens were close friends with four other couples consisting of four male physicists and their wives. The four physicists were: Samuel Allison, Elmer Dershem (1881–1965), Marcel Schein, and John Harry Williams (1908–1966). Allison, Williams, and Zachariasen took a number of canoeing vacations together, sometimes accompanied by Rudolph "Buddy" Thorness (1909–1969) and perhaps one or two other men. In 1974, Zachariasen retired from the University of Chicago and moved with his wife to Santa Fe, New Mexico, where they purchased the first house they ever owned. He continued to write scientific papers, often working with his friends Finley H. Ellinger and Robert A. Penneman, both from Los Alamos National Laboratory. Zachariasen also worked with Bernd Matthias, a professor at the University of California, San Diego. Zachariasen's son, Fredrik "Zach" Zachariasen (1931–1999), was a theoretical physicist, specializing in the interactions of elementary particles at high energies. Fredrik Zachariasen was a physics professor at Caltech and coauthored two books on high energy physics and another book related to the acoustics of antisubmarine warfare.
Influence on the science of glass In 1932 W. H. Zachariasen published "The Atomic Arrangement in Glass", a classic article that greatly influenced material scientists of that era. This article perhaps had more influence than any other published work on the science of glass. A glass has an amorphous structure, whereas a crystal has a long-range ordered structure; however, both glasses and crystals have the same building blocks, i.e. polyhedra consisting of cations and anions bound together. The crystallographer Zachariasen is generally credited as the greatest pioneer of the understanding of the structure of glass for his 1932 random network theory of glass. In this theory, the nature of bonding in the glass is the same as in the crystal, but the basic structural units in a glass are connected in a random manner in contrast to the periodic arrangement in a crystalline material. The work of Zachariasen provided a foundation for the development of the understanding of the structure of glass and the structure's relation with its chemical composition. According to Richard L. Lehman of Rutgers University, "Zachariasen considered the relative glass-forming ability of oxides and concluded that the ultimate condition for glass formation is that a substance can form extended three-dimensional networks lacking periodicity but with energy comparable with that of the corresponding crystal networks. From this condition he derived four rules for oxide structure that allow selection of those oxides that tend to form glasses. ... Overall, in spite of Zachariasen's mediocre prediction record, he has received great recognition as being the first to systematically address the relationship between atomic structure and glass forming ability." Assume that A {\displaystyle A} represents a metal atom, i.e. a cation. The four rules for the formation of a glass from an oxide A m O n {\displaystyle A_{m}O_{n}} are:
An oxygen atom is linked to no more than two glass-forming atoms A. The number of oxygen atoms around each glass-forming atom A is small, perhaps 3 or 4. Among the oxygen-containing polyhedra, a polyhedron cation A shares corners, but no sides or faces. For three-dimensional networks of oxygen-containing polyhedra, at least three corners must be shared.
… excerpt ends here. Continue reading the full article.
