X-ray

An X-ray is a form of high-energy electromagnetic radiation with a wavelength shorter than those of ultraviolet rays and longer than those of gamma rays. Roughly, X-rays have a wavelength ranging from 10 nanometers to 10 picometers, corresponding to frequencies in the range of 30 petahertz to 30 exahertz (3×1016 Hz to 3×1019 Hz) and photon energies in the range of 100 eV to 100 keV, respectively. X-rays were discovered in 1895 by the German scientist Wilhelm Conrad Röntgen, who named it X-radiation to signify an unknown type of radiation. X-rays can penetrate many solid substances such as construction materials and living tissue, so X-ray radiography is widely used in medical diagnostics (e.g., checking for broken bones) and materials science (e.g., identification of some chemical elements and detecting weak points in construction materials). However X-rays are ionizing radiation and exposure can be hazardous to health, causing DNA damage, cancer and, at higher intensities, burns and radiation sickness. Their generation and use is strictly controlled by public health authorities.

History

Pre-Röntgen observations and research

X-rays were originally noticed in science as a type of unidentified radiation emanating from discharge tubes by experimenters investigating cathode rays produced by such tubes, which are energetic electron beams that were first observed in 1869. Early researchers noticed effects that were attributable to them in many of the early Crookes tubes (invented around 1875). Crookes tubes created free electrons by ionization of the residual air in the tube by a high DC voltage of anywhere between a few kilovolts and 100 kV. This voltage accelerated the electrons coming from the cathode to a high enough velocity that they created X-rays when they struck the anode or the glass wall of the tube. The earliest experimenter thought to have (unknowingly) produced X-rays was William Morgan. In 1785, he presented a paper to the Royal Society of London describing the effects of passing electrical currents through a partially evacuated glass tube, producing a glow created by X-rays. This work was further explored by Humphry Davy and his assistant Michael Faraday. Starting in 1888, Philipp Lenard conducted experiments to see whether cathode rays could pass out of the Crookes tube into the air. He built a Crookes tube with a "window" at the end made of thin aluminium, facing the cathode so the cathode rays would strike it (later called a "Lenard tube"). He found that something came through, that would expose photographic plates and cause fluorescence. He measured the penetrating power of these rays through various materials. It has been suggested that at least some of these "Lenard rays" were actually X-rays. Hermann von Helmholtz formulated mathematical equations for X-rays. He postulated a dispersion theory before Röntgen made his discovery and announcement. He based it on the electromagnetic theory of light. However, he did not work with actual X-rays. In early 1890 photographer William Jennings and associate professor of the University of Pennsylvania Arthur W. Goodspeed were making photographs of coins with electric sparks. On 22 February after the end of their experiments two coins were left on a stack of photographic plates before Goodspeed demonstrated to Jennings the operation of Crookes tubes. While developing the plates, Jennings noticed disks of unknown origin on some of the plates, but nobody could explain them, and they moved on. Only in 1896 they realized that they accidentally made an X-ray photograph (they didn't claim a discovery). Also in 1890, Röntgen's assistant Ludwig Zehnder noticed a flash of light from a fluorescent screen immediately before the covered tube he was switching on punctured. When Stanford University physics professor Fernando Sanford conducted his "electric photography" experiments in 1891–1893 by photographing coins in the light of electric sparks, like Jennings and Goodspeed, he may have unknowingly generated and detected X-rays. His letter of January 6, 1893 to the Physical Review was duly published and an article entitled Without Lens or Light, Photographs Taken With Plate and Object in Darkness appeared in the San Francisco Examiner. In 1894, Nikola Tesla noticed damaged film in his lab that seemed to be associated with Crookes tube experiments and began investigating this invisible, radiant energy. After Röntgen identified the X-ray, Tesla began making X-ray images of his own using high voltages and tubes of his own design, as well as Crookes tubes.

Discovery by Röntgen

On 8 November 1895, German physics professor Wilhelm Röntgen discovered X-rays while experimenting with Lenard tubes and Crookes tubes and began studying them. He wrote an initial report "On a new kind of ray: A preliminary communication" and on 28 December 1895, submitted it to Würzburg's Physical-Medical Society journal. This was the first paper written on X-rays. Röntgen referred to the radiation as "X", to indicate that it was an unknown type of radiation. Some early texts refer to them as Chi-rays, having interpreted "X" as the uppercase Greek letter Chi, Χ. There are conflicting accounts of his discovery because Röntgen had his lab notes burned after his death, but this is a likely reconstruction by his biographers: Röntgen was investigating cathode rays from a Crookes tube which he had wrapped in black cardboard so that the visible light from the tube would not interfere, using a fluorescent screen painted with barium platinocyanide. He noticed a faint green glow from the screen, about 1 meter (3.3 ft) away. Röntgen realized some invisible rays coming from the tube were passing through the cardboard to make the screen glow. He found they could also pass through books and papers on his desk. Röntgen threw himself into investigating these unknown rays systematically. Two months after his initial discovery, he published his paper.

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