Zinc smelting is the process of converting zinc concentrates (ores that contain zinc) into pure zinc. Zinc smelting has historically been more difficult than the smelting of other metals, e.g. iron, because in contrast, zinc has a low boiling point. At temperatures typically used for smelting metals, zinc is a gas that will escape from a furnace with the flue gas and be lost, unless specific measures are taken to prevent it. The most common zinc concentrate processed is zinc sulfide, which is obtained by concentrating sphalerite via froth flotation. Secondary (recycled) zinc material, such as zinc oxide, is also processed with the zinc sulfide. Approximately 30% of all zinc produced is from recycled sources.
Methods There are two methods of smelting zinc: the pyrometallurgical process and the electrolysis process. Both methods are still used. Both of these processes share the same first step: roasting.
Roasting
Roasting is a process of oxidizing zinc sulfide concentrates at high temperatures into an impure zinc oxide, called "Zinc Calcine". The chemical reactions that take place are as follows:
2 ZnS + 3 O 2 ⟶ 2 ZnO + 2 SO 2 {\displaystyle {\ce {2ZnS + 3O2 -> 2ZnO + 2SO2}}}
2 SO 2 + O 2 ⟶ 2 SO 3 {\displaystyle {\ce {2SO2 + O2 -> 2SO3}}}
Approximately 90% of zinc in concentrates are oxidized to zinc oxide. However, at the roasting temperatures around 10% of the zinc reacts with the iron impurities of the zinc sulfide concentrates to form zinc ferrite. A byproduct of roasting is sulfur dioxide, which is further processed into sulfuric acid, a commodity. The linked refinery flow sheet shows a schematic of Noranda's eastern Canadian zinc roasting operation The process of roasting varies based on the type of roaster used. There are three types of roasters: multiple-hearth, suspension, and fluidized-bed.
Multiple-hearth roaster In a multiple-hearth roaster, the concentrate drops through a series of 9 or more hearths stacked inside a brick-lined cylindrical column. As the feed concentrate drops through the furnace, it is first dried by the hot gases passing through the hearths and then oxidized to produce calcine. The reactions are slow and can be sustained only by the addition of fuel. Multiple hearth roasters are unpressurized and operate at about 690 °C (1,270 °F). Operating time depends upon the composition of concentrate and the amount of the sulfur removal required. Multiple hearth roasters have the capability of producing a high-purity calcine.
Suspension roaster In a suspension roaster, the concentrates are blown into a combustion chamber very similar to that of a pulverized coal furnace. The roaster consists of a refractory-lined cylindrical steel shell, with a large combustion space at the top and 2 to 4 hearths in the lower portion, similar to those of a multiple hearth furnace. Additional grinding, beyond that required for a multiple hearth furnace, is normally required to ensure that heat transfer to the material is sufficiently rapid for the desulfurization and oxidation reactions to occur in the furnace chamber. Suspension roasters are unpressurized and operate at about 980 °C (1,800 °F).
Fluidized-bed roaster In a fluidized-bed roaster, finely ground sulfide concentrates are suspended and oxidized in feedstock bed supported on an air column. As in the suspension roaster, the reaction rates for desulfurization are more rapid than in the older multiple-hearth processes. Fluidized-bed roasters operate under a pressure slightly lower than atmospheric and at temperatures averaging 1,000 °C (1,830 °F). In the fluidized-bed process, no additional fuel is required after ignition has been achieved. The major advantages of this roaster are greater throughput capacities, greater sulfur removal capabilities, and lower maintenance.
Roast-Leach-Electrowin (RLE) process Also known as the hydrometallurgical process, electrolysis process, or electrolytic process, RLE is more widely used than the pyrometallurgical processes. The electrolysis process consists of 4 steps: leaching, purification, electrolysis, and melting and casting.
Leaching
The basic leaching chemical formula that drives this process is:
ZnO + SO 3 ⟶ ZnSO 4 {\displaystyle {\ce {ZnO + SO3 -> ZnSO4}}}
This is achieved in practice through a process called double leaching. The calcine is first leached in a neutral or slightly acidic solution (of sulfuric acid) in order to leach the zinc out of the zinc oxide. The remaining calcine is then leached in strong sulfuric acid to leach the rest of the zinc out of the zinc oxide and zinc ferrite. The result of this process is a solid and a liquid; the liquid contains the zinc and is often called leach product; the solid is called leach residue and contains precious metals (usually lead and silver) which are sold as a by-product. There is also iron in the leach product from the strong acid leach, which is removed in an intermediate step, in the form of goethite, jarosite, and haematite. There is still cadmium, copper, arsenic, antimony, cobalt, germanium, nickel, and thallium in the leach product. Therefore, it needs to be purified.
Purification
… excerpt ends here. Continue reading the full article.
